Preparation of Nanoparticles and Study of the Effect of Some of Their Physical Properties on Epoxy Polymer

Authors

Aya N. Abdullah, Physics Department, College of Education for Pure Science, Kirkuk University, Kirkuk, Iraq.Follow
Niran F. Abeduljabbar, Physics Department, College of Education for Pure Science, Tikrit University, Tikrit, Iraq

Abstract

ملخص. تم تحضيره بشكل مستقل بطرق مختلفة من أكاسيد النحاس والمغنيسيوم والزنك. تمت إضافة جسيمات نانوية مختلفة إلى الإيبوكسي بنسب وزنية (0، 2، 4، 6، 8، 10)٪ وزنية. ظهرت نتائج واضحة من حيود أشعة الشمس الساطعة هيكل الإيبوكسي في نظام، فاخره فاخره بميق نانوية بنسب إضافة أعلى، نجد ظهور مستقلة نانوية في شكل بلوري واضح، بينما نتائج المجهر الماسي الإلكتروني ح متزايدة في لاتساق والتوسع مع كل زيادة في نسبة التأمين التفاضلي، والتي ظهرت بوضوح خلال فحص EDX. كانت صلابة نوع Shore D هي الأفضل عند 10٪ لجميع أنواع الهواء، حيث كانت (90.2HD) لـ (EP-10٪ CuO) و (88.56HD) لـ (EP-10٪ MgO) و (87.5HD) لـ (EP-10٪ ZnO). أما بالنسبة لمقاومة التأثير، فقد اخترعت جسيمات أكسيد مغنسيوم نانوية أفضل قيمة عند 10٪ عند (12.3KJ/m2 ⁾ . وقد وجد أن قيمة الموصلية الحرارية وصلت إلى أعلى مستوياتها عند نسبة EP-10٪ CuO حيث إجمالي (0.5528W/mK)، بينما بالنسبة للمركب EP-10٪ ZnO عند نفس الوقت كانت واضحة (0.4683W/mK بينما)، كانت القيمة الأقل في مركب EP-10٪ MgO عند نفس نسبة الإضافة حيث تبقى (0.0453W/mK). وجد أن تحافظ على أفضل قيمة لها عند نسبة EP-10%CuO حتى النهاية (0.5528W/mK)، أما بالنسبة للمركب EP-10%ZnO فأنت أفضل ما دامت لمدة طويلة (0.4683W/mK)، في حين كانت القيمة الأقل لها في المركبة EP-10%MgO وأنت نفس نسبة الإضافة حيث تستمر (0.0453W/mK).

Recommended Citation

Abdullah, Aya N. and Abeduljabbar, Niran F. (2025) "Preparation of Nanoparticles and Study of the Effect of Some of Their Physical Properties on Epoxy Polymer," Al-Bahir Journal for Engineering and Pure Sciences: Vol. 6: Iss. 2, Article 5.
Available at: https://doi.org/10.55810/2313-0083.1095

References

[1] Mi X, Liang N, Xu H, Wu J, Jiang Y, Nie B, et al. Toughness and its mechanisms in epoxy resins. Prog Mater Sci 2022;130: 100977. 150 AL-BAHIR JOURNAL FOR ENGINEERING AND PURE SCIENCES 2025;6:141e151

[2] Shubham, Ray BC. Introduction to composite materials. In: Fiber reinforced polymer (FRP) composites in ballistic protection: microstructural and micromechanical perspectives. Singapore: Springer Nature Singapore; 2024. p. 1e20.

[3] Awaja F, Zhang S, Tripathi M, Nikiforov A, Pugno N. Cracks, microcracks and fracture in polymer structures: formation, detection, autonomic repair. Prog Mater Sci 2016;83:536e73.

[4] Meyers MA, Mishra A, Benson DJ. Mechanical properties of nanocrystalline materials. Prog Mater Sci 2006;51(4):427e556.

[5] Rathod VT, Kumar JS, Jain A. Polymer and ceramic nanocomposites for aerospace applications. Appl Nanosci 2017;7: 519e48.

[6] Silvestre J, Silvestre N, De Brito J. An overview on the improvement of mechanical properties of ceramics nanocomposites. J Nanomater 2015;2015(1):106494.

[7] Shirvanimoghaddam K, Balaji KV, Yadav R, Zabihi O, Ahmadi M, Adetunji P, et al. Balancing the toughness and strength in polypropylene composites. Compos B Eng 2021; 223:109121.

[8] Moradpoor H, Safaei M, Mozaffari HR, Sharifi R, Imani MM, Golshah A, et al. An overview of recent progress in dental applications of zinc oxide nanoparticles. RSC Adv 2021; 11(34):21189e206.

[9] Ghazal NA, Majeed ZN, Darweesh SY. The effect of adding different percentages manganese on some mechanical and magnetic properties of composite (Al-Cu). AIP Conf Proc 2024, March;2885(1). AIP Publishing.

[10] Wu C, Wang Q, Wang X, Sun S, Wang Y, Wu S, et al. Al2O3 nanoparticles integration for comprehensive enhancement of eutectic salt thermal performance: experimental design, molecular dynamics calculations, and system simulation studies. Energy 2024;292:130567.

[11] Terna AD, Elemike EE, Mbonu JI, Osafile OE, Ezeani RO. The future of semiconductors nanoparticles: synthesis, properties and applications. Mater Sci Eng, B 2021;272:115363.

[12] Dahham AT, Jassim TQ, Darweesh SY. Study the effect of adding nano-magnesium oxide on some structural and mechanical properties of (Cu-10 % Fe). AIP Conf Proc 2023, December;2977(1). AIP Publishing.

[13] Karim AS, Majeed ZN, Darweesh SY. The effect of nanostructured zirconia reinforcement on the mechanical and structural properties of a copper-based system. Mater Sci Forum 2021, August;1039:297e306. Trans Tech Publications Ltd.

[14] Cao H, Jian X, Zhang D, Ling W, Zhang G, Zhang Y, et al. Amphiphilicity-driven octaphenyl polyoxyethylenes regulate soft microcapsules flexibility for better foliar adhesion and pesticide utilization. Adv Agrochem 2024;3(4):316e27.

[15] Lortholary A, Largillier R, Weber B, Gladieff L, Alexandre J, Durando X, et al. Weekly paclitaxel as a single agent or in combination with carboplatin or weekly topotecan in patients with resistant ovarian cancer: the CARTAXHY randomized phase II trial from Groupe d'Investigateurs Nationaux pour l'Etude des Cancers Ovariens (GINECO). Ann Oncol 2012;23(2):346e52.

[16] Wiley. Characterization and analysis of polymers. John Wiley & Sons; 2008.

[17] Yahya MM, Aleabi SH. Improvement some mechanical properties (impact strength, hardness, tensile strength) and thermal conductivity for epoxy coating. AIP Conf Proc 2024, March;2885(1). AIP Publishing.

[18] Lin Y, Huang X, Chen J, Jiang P. Epoxy thermoset resins with high pristine thermal conductivity. High Volt 2017;2(3):139e46

. [19] Fu YX, He ZX, Mo DC, Lu SS. Thermal conductivity enhancement with different fillers for epoxy resin adhesives. Appl Therm Eng 2014;66(1e2):493e8.

[20] Ahmed MN, Daham NA, Darweesh SY. Structural and mechanical properties for (Ni-WC) system by using thermal spray. AIP Conf Proc 2024, March;2885(1). AIP Publishing.

[21] Dong R, Gong W, Guo Q, Liu H, Yu DG. Synergistic effects of radical distributions of soluble and insoluble polymers within electrospun nanofibers for an extending release of ferulic acid. Polymers 2024;16(18):2614.

[22] Salih EJ, Allah SMA, Darweesh SY, Mohammed HA. Study of some of the physical variables of a metal-based system using the powder method. J Phys 2021, September;1999(1): 012068. IOP Publishing.

[23] Almuqrin AH, Sayyed MI, Khandaker MU, Aloraini DA, Rashad M, Elsafi M. Effect of concentration of CuO on radiation shielding characteristics of Epoxy-resin materials. Radiat Phys Chem 2024:111918.

[24] Yaseen M, Khan A, Humayun M, Bibi S, Farooq S, Bououdina M, et al. Fabrication and characterization of CuOeSiO2/PVA polymer nanocomposite for effective wastewater treatment and prospective biological applications. Green Chem Lett Rev 2024;17(1):2321251.

[25] Salih WA, Allah SMA, Darweesh SY. Effect of spray angle on some physical properties of a ceramic system produced by thermal spraying coating. Al-Bahir J Eng Pure Sci 2023;2(2):4.

[26] Humeedi SH, Shafeek NA, Ahmeed HH, Darweesh SY. The effect of adding titanium nanoparticle oxide on the physical properties of nickel by powder method. J Phys Conf 2020, November;1664(1):012078. IOP Publishing.

[27] Ota S, Harada M. Thermal conductivity enhancement of liquid crystalline epoxy/MgO composites by formation of highly ordered network structure. J Appl Polym Sci 2021; 138(19):50367.

[28] Salahuddin NA, El-Kemary M, Ibrahim EM. High-performance flexible epoxy/ZnO nanocomposites with enhanced mechanical and thermal properties. Polym Eng Sci 2017; 57(9):932e46.

[29] Vyhnankova M, Hodul J, Byd zovský J. Epoxy resin coatings crystallization and influence of crystallinity on shore hardness and tensile properties. Solid State Phenom 2018;276: 173e8.

30] Rasheed ZN. Study of the effect of the variation effect of water temperatures on shore (D) hardness for some polymers. Al-Nahrain J Sci 2013;16(3):110e8.

[31] Mustafa A, Aloyaydi B, Sivasankaran S, Al-Mufadi FA. Shore hardness characterization of FDM printed PLA/Epoxy/MGFs composite material structure. In: Recent advances in manufacturing processes and systems: select proceedings of RAM 2021. Singapore: Springer Nature Singapore; 2022. p. 919e26.

[32] Natrayan L. and Al2O3 nanofillers epoxy hybrid composites. In: Sustainable structural materials: from fundamentals to manufacturing, properties and applications. vol. 275; 2025.

[33] Soudagar MEM, Bashir MN, Vijayan DS, Hossain I, Kannan S, Al Obaid S, et al. Study of antimicrobial and mechanical behaviors on kapok fiber reinforced bran particulates blended epoxy matrix composite. Therm Sci Eng Prog 2025;57:103123.

[34] Boulebnane A, Djeghader D, Tioua T. Weibull analysis of Charpy impact test in short date palm fiber reinforced epoxy composite. Period Polytech Civ Eng 2024;68(1):122e30.

[35] Oztas € ¸ B, Korkmaz Y, Çelik H_ I. Image analyses of artificially damaged carbon/glass/epoxy composites before and after impact load. Heliyon 2024;10(4):e25876.

[36] Xin Y, Yan H, Cheng S, Li H. Drop weight impact tests on composite sandwich panel of aluminum foam and epoxy resin. Mech Adv Mater Struct 2021;28(4):343e56.

[37] Ibraheem AM, Allah SMA, Darweesh SY. Enhancement the properties of aluminum by adding boron carbide by the powder method. J Phys Conf 2021, September;1999(1):012074. IOP Publishing.

[38] Antar RS, Darweesh SY, Ridha FW. Production of a double cermet coating to treatment of the turbine blades. Eng Res Express 2024;6(1):015407.

[39] Humeedi SH, Abdulkareem SM, Darweesh SY. The synthetic and mechanical properties of a silica matrix cermet composite. J Wuhan Univ Tech Mater Sci Ed 2022;37(3): 423e8.

[40] Cheng P, Chen X, Gao H, Zhang X, Tang Z, Li A, et al. Different dimensional nanoadditives for thermal conductivity enhancement of phase change materials: fundamentals and applications. Nano Energy 2021;85:105948